Material Safety Data Sheet
Trimethylamine solution 25% wt% in propylene glycol   

Section 1 - Chemical Product and Company Identification
MSDS Name: Trimethylamine solution 25% wt% in propylene glycol 
Catalog Numbers:SC-46821

Section 2 - Composition, Information on Ingredients 
CAS#1785-61-1
Chemical Name:Trimethylamine solution 25% wt% in propylene glycol
Percent: 25% wt% in propylene glycol
EINECS/ELINCS: Not available
Hazard Codes: F, Xi, Xn
Risk Phrases: 11-20-37/38-41

Section 3 - Hazards Identification 
3.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
F Highly flammable R11
Xn Harmful R20
Xi Irritant R41, R37/38
For the full text of the R-phrases mentioned in this Section, see Section 16.
3.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram 
Signal word: Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261 Avoid breathing vapours.
P280 Wear protective gloves/ eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard Statements: none

According to European Directive 67/548/EEC as amended.
Hazard symbol(s) F Highly flammable
Xn Harmful
R-phrase(s)
R11 Highly flammable.
R20 Harmful by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
S-phrase(s)
S16 Keep away from sources of ignition - No smoking.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39 Wear eye/face protection.

Section 4 - First Aid Measures 
4.1 Description of first aid measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed: no data available

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information: Use water spray to cool unopened containers.

Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.  Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections: For disposal see section 13.

Section 7 - Handling and Storage 
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Handle and open container with care.
7.3 Specific end use(s): Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Section 8 - Exposure Controls, Personal Protection 
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment
Eye/face protection
Tightly fitting safety goggles.  Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Section 9 - Physical and Chemical Properties 
Physical State: Liquid
Color: Colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available. 
Viscosity: Not available.
Boiling Point: No data available.  
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available
Flash Point: No data available
Decomposition Temperature: Not available
Water Solubility: Not available
Specific Gravity/Density: No data available.
Molecular Formula: C3H9N
Molecular Weight: 59.11

Section 10 - Stability and Reactivity 
10.1 Reactivity: no data available
10.2 Chemical stability: Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions: no data available
10.4 Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5 Incompatible materials: Zinc, Oxidizing agents, Strong oxidizing agents, Copper, Acid chlorides, Acid anhydrides, Reducing agents, Chloroformates, Brass, Magnesium, Tin/tin oxides, Mercury/mercury oxides.
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5 

Section 11 - Toxicological Information 
11.1 Information on toxicological effects
Acute toxicity: no data available
Inhalation: no data available
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitisation: no data available
Germ cell mutagenicity: no data available
Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: no data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available
Additional Information
RTECS: Not available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea, Gastrointestinal disturbance, Vomiting, Central nervous system depression

Section 12 - Ecological Information 
12.1 Toxicity: no data available
12.2 Persistence and degradability: no data available
12.3 Bioaccumulative potential: no data available
12.4 Mobility in soil: no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects: no data available

Section 13 - Disposal Considerations 
Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging:Dispose of as unused product.

Section 14 - Transport Information 
14.1 UN number
ADR/RID: 2924                                            IMDG: 2924                                         IATA: 2924
14.2 UN proper shipping name
ADR/RID:  FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Propane-1,2-diol, Trimethylamine)
IMDG:  FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Propane-1,2-diol, Trimethylamine)
IATA:  Flammable liquid, corrosive, n.o.s. (Propane-1,2-diol, Trimethylamine)
14.3 Transport hazard class(es)
ADR/RID: 3 (8)                                            IMDG: 3 (8)                                          IATA: 3 (8)
14.4 Packaging group
ADR/RID: II                                                  IMDG: II                                               IATA: II
14.5 Environmental hazards
ADR/RID: no                                        IMDG Marine pollutant: no                  IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information 
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture： no data available
15.2 Chemical Safety Assessment： For this product a chemical safety assessment was not carried out

Section 16 - Additional Information
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox. Acute toxicity
Eye Dam. Serious eye damage
Flam. Gas Flammable gases
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H302 + H332 Harmful if swallowed or if inhaled
H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
Press. Gas Gases under pressure
Skin Irrit. Skin irritation
STOT SE Specific target organ toxicity - single exposure
Full text of R-phrases referred to under sections 2 and 3
F+ Extremely flammable
R11 Highly flammable.
R12 Extremely flammable.
R20 Harmful by inhalation.
Xn Harmful
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.

While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.