Material Safety Data Sheet
Azoxystrobin
Section 1 - Chemical Product and Company Identification
MSDS Name: Azoxystrobin
Catalog Numbers: SC-24628
Identified uses : Laboratory chemicals, Manufacture of substances

Section 2 - Composition, Information on Ingredients
CAS#131860-33-8
Chemical Name: Azoxystrobin
EINECS/ELINCS: Not available
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Inhalation (Category 3), H331
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
For the full text of the H-Statements mentioned in this Section, see Section 16
Classification according to EU Directives 67/548/EEC or 1999/45/EC
T      Toxic                             R23
N      Dangerous for the environment    R50/53
For the full text of the R-phrases mentioned in this Section, see Section 16.   2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram             
Signal word            Danger
Hazard statement(s)
H331                  Toxic if inhaled.
H410                  Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P261                  Avoid breathing dust.
P273                  Avoid release to the environment.
P311                  Call a POISON CENTER or doctor/ physician.
P501                  Dispose of contents/ container to an approved waste disposal plant.  Supplemental Hazard Statements     none 

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
May be harmful if inhaled. Causes respiratory tract irritation. 

Potential Health Effects
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Skin: Harmful if absorbed through skin. May cause skin irritation.
Eyes: Causes eye burns.
Ingestion: Harmful if swallowed.

Section 4 - First Aid Measures 
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact.
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. 
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available  
Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas 
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
No data available 
Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.  6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 
6.4 Reference to other sections
For disposal see section 13. 

Section 7 - Handling and Storage 
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. 
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Light sensitive.  7.3 Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated  

Section 8 - Exposure Controls, Personal Protection 
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). 
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. 
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 

Section 9 - Physical and Chemical Properties 
Physical State: Powder.
Color: White
Odor: Not available
pH: Not available.
Vapor Pressure: Not available 
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available
Autoignition Temperature: Not available
Flash Point: Not available.
Decomposition Temperature:Not available.
Solubility: Not available
Specific Gravity/Density:Not available.
Molecular Formula: C22H17N3O5
Molecular Weight: 403.39

Section 10 - Stability and Reactivity 
10.1 Reactivity: No data available
10.2 Chemical stability: Stable under recommended storage conditions. 
10.3 Possibility of hazardous reactions: No data available
10.4 Conditions to avoid: No data available
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

Section 11 - Toxicological Information 
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 375 mg/kg
LD50 Dermal - rabbit - 1.400 mg/kg
Remarks: Behavioral:Ataxia. Skin irritation
Skin corrosion/irritation
Skin - rabbit - Mild skin irritation - 24 h
Serious eye damage/eye irritation
Eyes - rabbit - Severe eye irritation - 24 h
Respiratory or skin sensitization
no data available
May cause sensitization by inhalation.
Germ cell mutagenicity
no data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: no data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available
Additional Information: RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12 - Ecological Information 
12.1 Toxicity
Toxicity to fish :LC50 - Oncorhynchus mykiss (rainbow trout) - > 150 mg/l - 96,0 hLC50 - Oncorhynchus mykiss (rainbow trout) - > 150mg/l - 96,0 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,259 mg/l - 48 h  
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.

Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.  Contaminated packaging
Dispose of as unused product. 

Section 14 - Transport Information 
14.1 UN number
ADR/RID: 2811             IMDG: 2811                   IATA: 2811
14.2 UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (Azoxystrobin)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (Azoxystrobin)
IATA: Toxic solid, organic, n.o.s. (Azoxystrobin)
14.3 Transport hazard class(es)
ADR/RID: 6.1               IMDG: 6.1                   IATA: 6.1
14.4 Packaging group
ADR/RID: III                IMDG: III                    IATA: III
14.5 Environmental hazards
ADR/RID: yes              IMDG Marine pollutant: yes     IATA: no
14.6 Special precautions for user
no data available 
Section 15 - Regulatory Information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
no data available

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.