Material Safety Data Sheet
4-bromopyridine
Section 1 - Chemical Product and Company Identification
MSDS Name: 4-bromopyridine
Catalog Numbers: SC-20313
Section 2 - Composition, Information on Ingredients
CAS#1120-87-2
Chemical Name : 4-bromopyridine
Percent 99%
EINECS/ELINCS : 214-320-5
Hazard Symbols: Xi
Risk Phrases: 36/37/38
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye: Cause eye irritation.
Skin: May be harmful if absorbed through skin. Causes skin irritation.
Ingestion: May be harmful if swallowed.
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Chronic: Limited evidence of a carcinogenic effect.
Section 4 - First Aid Measures
Consult a physician. Show this safety data sheet to the doctor in attendance.
Eyes: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin: Wash off with soap and plenty of water. Consult a physician.
Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Inhalation: If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
Section 5 - Fire Fighting Measures
General Information: Wear self contained breathing apparatus for fire fighting if necessary.
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Section 6 - Accidental Release Measures
General Information: Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Do not let product enter drains.
Spills/Leaks: Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.
Section 7 - Handling and Storage
Handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.
Storage: Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes: Safety glasses with side-shields conforming to EN166
Skin: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Clothing: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with
gloves.
Respirators: Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Section 9 - Physical and Chemical Properties
Physical State: crystalline
Color: light yellow to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point:: Not available.
Freezing/Melting Point:: 53-56 °C(lit.)
Auto ignition Temperature: Not available.
Flash Point: 224 °F
Decomposition Temperature: Not available.
Solubility: not available
Specific Gravity/Density: Not available.
Molecular Formula: C5H4BrN
Molecular Weight:: 158
Section 10 - Stability and Reactivity
Chemical Stability: Stable under recommended storage conditions.
Conditions to Avoid: no data available
Incompatibilities with Other Materials: Strong oxidizing agents
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Hydrogen iodide
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 1120-87-2:
LD50/LC50: RTECS:
CAS# 1120-87-2:
Carcinogenicity:
4-bromopyridine ,99% - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Other Studies: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information.
Section 12 - Ecological Information
Not available.
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
ADR/RID Not dangerous goods
IMDG Not dangerous goods
IATA Not dangerous goods
Section 15 - Regulatory Information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Hazard Class: no data
Risk Phrases:
R 36/37/38 Irritating to the eyes, the respiratory system ,and the skin .
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S 36 Wear suitable protective clothing
WGK Germany 3
Section 16 - Additional Information
The above information is believed to be accurate but does not suppose to be all inclusive and shall be used only as a guide. Reagent World makes no warranty of merchantability or any other warranty, express or implied, with respect to such information. Users should make their own investigations to determine the accountability of the information for their purposes in particular. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential of exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.
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