Material Safety Data Sheet
[1,1'-Biphenyl]-4,4'-diamine, N,N,N',N'-tetrakis([1,1'-biphenyl]-4-yl)-
Section 1 - Chemical Product and Company Identification
MSDS Name: [1,1'-Biphenyl]-4,4'-diamine, N,N,N',N'-tetrakis([1,1'-biphenyl]-4-yl)-
Catalog Numbers: 86-66309

Section 2 - Composition, Information on Ingredients 
CAS# 164724-35-0
Chemical Name: [1,1'-Biphenyl]-4,4'-diamine, N,N,N',N'-tetrakis([1,1'-biphenyl]-4-yl)-
Percent  95.0%
Labelling according Regulation (EC) No 1272/2008 [CLP]
Signal word: Warning
Hazard statement(s):
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard Statements: none

Section 3 - Hazards Identification 
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. Causes skin irritation.
Eyes: Causes serious eye irritation.

Section 4 - First Aid Measures
4.1 Description of first aid measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
4.3 Indication of any immediate medical attention and special treatment needed: no data available

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information: no data available

Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
6.2 Environmental precautions: Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections: For disposal see section 13.

Section 7 - Handling and Storage 
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end uses
no data available

Section 8 - Exposure Controls, Personal Protection 
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and  at the end of workday.
Personal protective equipment

Eye/face protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and  the standard EN 374 derived from it.
Body Protection: impervious clothing, The type of protective equipment must be selected according to the  concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher  level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.  Use respirators and components tested and approved under appropriate government standards  such as NIOSH (US) or CEN (EU).

Section 9 - Physical and Chemical Properties 
Physical State: Solid
Color:
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available
Melting point: Not available
Autoignition Temperature: Not available
Flash Point: Not available
Explosion Limits: Lower: Not available
Explosion Limits: Upper: Not available
Decomposition Temperature:Not available.
Solubility:
Specific Gravity/Density:  1.19
Molecular Formula: C60H44N2 
Molecular Weight: 793.022 

Section 10 - Stability and Reactivity 
Chemical Stability: No data.
Conditions to Avoid: No data.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen fluoride
Hazardous Polymerization:Has not been reported.

Section 11 - Toxicological Information
RTECS#: CAS# 164724-35-0: None listed     
Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Other Studies: The toxicological properties have not been fully investigated.

Section 12 - Ecological Information 
Nor available

Section 13 - Disposal Considerations 
13.1 Waste treatment methods
Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed  professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.

Section 14 - Transport Information 
14.1 UN number
ADR/RID:  -                          IMDG:  -                                   IATA:  -
14.2 UN proper shipping name
ADR/RID:  Not dangerous goods
IMDG:  Not dangerous goods
IATA:  Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID:  -                           IMDG:  -                                  IATA:  -
14.4 Packaging group
ADR/RID:  -                           IMDG:  -                                  IATA:  -
14.5 Environmental hazards
ADR/RID: no                         IMDG Marine pollutant: no      IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information 
European/International Regulations
     According to European Directive 67/548/EEC as amended.
           Hazard symbol(s)

                 R-phrase(s)
                    R36/37/38 Irritating to eyes, respiratory system and skin.
                 S-phrase(s)
 
                  S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
                    S36 Wear suitable protective clothing.

           WGK (Water Danger/Protection)
                   CAS# 164724-35-0: Not available

 Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.