Material Safety Data Sheet
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL]PALLADIUM(II) CHLORIDE
 
Section 1 - Chemical Product and Company Identification
MSDS Name: [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL]PALLADIUM(II) CHLORIDE 
Catalog Numbers: 86-65009

Section 2 - Composition, Information on Ingredients 
CAS#127593-28-6
Chemical Name: [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL]PALLADIUM(II) CHLORIDE  
Percent  95%
EINECS/ELINCS: Not available
Hazard Symbols: Xn
Risk Phrases: 20/21/22-36/37/38

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin

Potential Health Effects
Eye: Causes serious eye irritation.
Skin: Harmful if absorbed through skin. Causes skin irritation.
Ingestion: Harmful if swallowed.
Inhalation: Harmful if inhaled. Causes respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures 
Eyes: Flush eyes with water as a precaution.
Skin: Wash off with soap and plenty of water.
Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water.
Inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Notes to Physician: Treat symptomatically and supportively

Section 5 - Fire Fighting Measures 
General Information: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self contained breathing apparatus for fire fighting if necessary.

Section 6 - Accidental Release Measures 
Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapors, mist or gas.
Environmental precautions: Do not let product enter drains.
Methods and materials for containment and cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections: For disposal see section 13

Section 7 - Handling and Storage 
Precautions for safe handling: Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Handle and store under inert gas. Air sensitive.

Section 8 - Exposure Controls, Personal Protection 
Engineering Controls: Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment
Eyes: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9 - Physical and Chemical Properties 
Physical State: Powder
Color: Red brown
Odor: Not available
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available

Freezing/Melting Point: Not available
Autoignition Temperature: Not available
Flash Point: Not available
Decomposition Temperature: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C44H32Cl2P2Pd
Molecular Weight: 800

Section 10 - Stability and Reactivity 
Chemical Stability: Not available.
Conditions to Avoid: Not available.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: has not been reported.

Section 11 - Toxicological Information 
RTECS#: Not available
CAS#127593-28-6
LD50/LC50: RTECS: Not available
Carcinogenicity:IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL]PALLADIUM(II) CHLORIDE,95%- Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other Studies: The toxicological properties have not been fully investigated.

Section 12 - Ecological Information 
Additional ecological information:
General notes: no data available

Section 13 - Disposal Considerations
Dispose of in a manner consistent  with federal, state, and local regulations.

Section 14 - Transport Information 
14.1 UN number
ADR/RID: -                     IMDG: -                                                  IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: -                   IMDG: -                                                    IATA: -
14.4 Packaging group 
ADR/RID: -                   IMDG: -                                                     IATA: -
14.5 Environmental hazards
ADR/RID: no                IMDG Marine Pollutant: no                       IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information
European/International Regulations
      European Labeling in Accordance with EC Directives
           Hazard Symbols: Xn
           Risk Phrases:
                   R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
                   R36/37/38: Irritating to eyes, respiratory system and skin
           Safety Phrases:
                  S26: Avoid contact with eyes
                  S37/39: Wear suitable gloves and eye/face protection

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.