Material Safety Data Sheet
7-fluoro-1H-indazole-3-carboxylic acid      

Section 1 - Chemical Product and Company Identification
MSDS Name: 7-fluoro-1H-indazole-3-carboxylic acid     
Catalog Numbers: 86-63091

Section 2 - Composition, Information on Ingredients 
CAS#959236-59-0
Chemical Name: 7-fluoro-1H-indazole-3-carboxylic acid  
Percent  95%min
EINECS/ELINCS: Not available
Hazard Codes: Xi
Risk Phrases: 36/37/38

Section 3 - Hazards Identification 
3.1 Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to eyes, respiratory system and skin.
3.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram 
Signal word: Warning
Hazard statement(s)
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard Statements:  none
According to European Directive 67/548/EEC as amended.
Hazard symbol(s) 
R-phrase(s)
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
3.3 Other hazards None

Section 4 - First Aid Measures 
Eyes:Flush eyes with plentyofwater occasionallylifting the upper and lower lids.Get medical aid.
Skin:Get medical aid. Flush skin with plentyofwater while removing contaminated clothing and shoes.
Ingestion:Get medical aid.Wash mouth outwith water.
Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Section 5 - Fire Fighting Measures 
General Information:As in anyfire,wear a self-contained breathing apparatus and full protective gear.
ExtinguishingMedia:Use water spray, drychemical, carbon dioxide or chemical foam

Section 6 - Accidental Release Measures 
General Information:Use proper personal protective equipment.
Spills/Leaks:Vacuum or sweep up material and place into suitable disposalcontainer. Avoid generating dusty conditions

Section 7 - Handling and Storage 
Handling: Avoid breathing dust, vapor, mist or gas. Avoid contact with eyes, skin.
Storage: Stable Store in a cool, dry, well-ventilated area away from incompatible

Section 8 - Exposure Controls, Personal Protection 
EngineeringControls:Facilities storing or utilizing this material should be equipped with an eyewash facility and safetyshower.Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment
Eyes: Wear chemical safetygoggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Wear appropriate respirators where necessary

Section 9 - Physical and Chemical Properties 
Physical State: powder
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.  
Viscosity: Not available.
Boiling Point: 445.851 °C at 760 mmHg.   
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available
Flash Point: Not available.
Decomposition Temperature: Not available
Water Solubility: Slightly soluble.
Specific Gravity/Density: Not available
Molecular Formula: C8H5FN2O2
Molecular Weight: 180.14g/mol

Section 10 - Stability and Reactivity 
Chemical Stability:This product is relatively unstable under normal temperature.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous combustion or Decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen fluoride.

Section 11 - Toxicological Information 
11.1 Information on toxicological effects
Acute toxicity: no data available
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitization: no data available
Germ cell mutagenicity: no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available

Potential health effects
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. Causes skin irritation.
Eyes: Causes serious eye irritation.
Signs and Symptoms of Exposure
Cough, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Additional Information
RTECS: Not available
Additional Information
RTECS:No data available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12 - Ecological Information 
12.1 Toxicity: no data available
12.2 Persistence and degradability: no data available
12.3 Bioaccumulative potential: no data available
12.4 Mobility in soil: no data available
12.5 Results of PBT and vPvB assessment: no data available
12.6 Other adverse effects: no data available

Section 13 - Disposal Considerations 
13.1 Waste treatment methods
Product: This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging: Dispose of as unused product.

Section 14 - Transport Information 

14.1 UN number
ADR/RID: _                                         IMDG: _                                         IATA: _
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: _                                         IMDG: _                                         IATA: _
14.4 Packaging group
ADR/RID: _                                         IMDG: _                                         IATA: _
14.5 Environmental hazards
ADR/RID: No                                      IMDG Marine pollutant: No            IATA: No
14.6 Special precautions for user
No data available.

Section 15 - Regulatory Information 
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: no data available
15.2 Chemical Safety Assessment: no data available

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.