Material Safety Data Sheet
3-Pyrrolidinecarboxylic acid, ethyl ester

Section 1 - Chemical Product and Company Identification
MSDS Name: 3-Pyrrolidinecarboxylic acid, ethyl ester
Catalog Numbers: 86-49440

Section 2 - Composition, Information on Ingredients 
CAS# 72925-15-6
Chemical Name: 3-Pyrrolidinecarboxylic acid, ethyl ester
Percent  97%
EINECS/ELINCS

Section 3 - Hazards Identification 
3.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Harmful if swallowed. Irritating to eyes, respiratory system and skin.
3.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram 
Signal word: Warning
Hazard statement(s)
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Supplemental Hazard Statements: None
According to European Directive 67/548/EEC as amended
Hazard symbol(s)
R-phrase(s)
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
3.3 Other hazards None

Section 4 - First Aid Measures
Eyes:Flush eyes with plentyofwater occasionallylifting the upper and lower lids.Get medical aid.
Skin:Get medical aid. Flush skin with plentyofwater while removing contaminated clothing and shoes.
Ingestion:Get medical aid.Wash mouth outwith water.
Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Section 5 - Fire Fighting Measures 
General Information:As in anyfire,wear a self-contained breathing apparatus and full protective gear.
ExtinguishingMedia:Use water spray, drychemical, carbon dioxide or chemical foam.

Section 6 - Accidental Release Measures 
General Information: Use proper personal protective equipment.
Spills/Leaks: Vacuum or sweep up material and place into suitable disposalcontainer. Avoid generating dusty conditions.

Section 7 - Handling and Storage 
Handling: Avoid breathing dust, vapor, mist or gas. Avoid contactwith eyes, skin.
Storage: Storage temperature: 2 - 4 °C and Keep container tightlyclosed in a dryand well-ventilated place.

Section 8 - Exposure Controls, Personal Protection 
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment
Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing:  Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties 
Physical State:  Viscous solid
Color: Brown-yellow
Odor: Not available
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 191.3 °Cat 760 mmHg
Freezing/Melting Point: N/A
Autoignition Temperature: N/A
Flash Point: N/A
Upper exp. Limit: N/A
Lower exp. Limit: N/A
Fire Potential: Flammable liquid and vapor.
Decomposition Temperature:Not available.
vapor pressure: N/A
Solubility in water: Slightlysoluble.
Specific Gravity/Density: N/A
Molecular Formula: C7H13NO2
Molecular Weight: 143.184g/mo

Section 10 - Stability and Reactivity 
Chemical Stability: This product is relativelyunstable under normal temperature.
IncompatibilitieswithOther Materials: Strong oxidizing agents.
Hazardous combustionor Decompositionproducts: Carbon monoxide, carbon dioxide, and nitrogen oxides.

Section 11 - Toxicological Information 
11.1 Informationontoxicological effects
Acute toxicity: No data available.
Skincorrosion/irritation: No data available.
Serious eye damage/eye irritation: No data available.
Respiratoryor skinsensitization: No data available.
Germcellmutagenicity: No data available.
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No data available.
Specific target organtoxicity- single exposure: No data available.
Specific target organtoxicity-repeatedexposure: No data available.
Aspirationhazard: No data available.
Additional Information: RTECS:No data available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12 - Ecological Information 
Toxicity: a health hazard

Section 13 - Disposal Considerations
Product: Offer surplus and non-recyclable solutions to a licensed disposal company.Contact a licensed professional waste disposal service to dispose of this material.Dissolve or mixthe material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminatedpackaging: Dispose of as unused product.

Section 14 - Transport Information 
14.1 UN number
ADR/RID: _                                                  IMDG: _                                              IATA: _
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: _                                                  IMDG: _                                              IATA: _
14.4 Packaging group
ADR/RID: _                                                  IMDG: _                                              IATA: _
14.5 Environmental hazards

ADR/RID: No                                               IMDG Marine pollutant: No                 IATA: No
14.6 Special precautions for user:: No data available.

Section 15 - Regulatory Information 
This safetydatasheet complies with the requirements ofRegulation (EC) No. 1907/2006.
Safety, healthandenvironmentalregulations/legislationspecific for the substance or mixture: No data available.
Chemical SafetyAssessment:No data available

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.