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Procaine hydrochloride

Material Safety Data Sheet
Procaine hydrochloride  

Section 1 - Chemical Product and Company Identification
MSDS Name: Procaine hydrochloride 
Catalog Numbers: 86-36447

Section 2 - Composition, Information on Ingredients 
CAS# 51-05-8
Chemical Name: Procaine hydrochloride  
Percent  99%
EINECS/ELINCS: 200-077-2
Hazard Symbols: T
Risk Phrases: 25-43

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 3)
Skin sensitization (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Toxic if swallowed. May cause sensitization by skin contact.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram 
Signal word: Danger
Hazard statement(s)
H301 Toxic if swallowed.
H317 May cause an allergic skin reaction.
Precautionary statement(s)
P280 Wear protective gloves.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard Statements: none
 
Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
Harmful if swallowed. Cause irritating to eyes, respiratory system and skin

Potential Health Effects
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion: Toxic if swallowed.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Chronic: No information found.

Section 4 - First Aid Measures 
4.1 Description of first aid measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled:If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact: Flush eyes with water as a precaution.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed:no data available
Notes to Physician: Treat symptomatically and supportively

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.

Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections: For disposal see section 13.

Section 7 - Handling and Storage 
7.1 Precautions for safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Air and light sensitive.
7.3 Specific end uses: no data available

Section 8 - Exposure Controls, Personal Protection 
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9 - Physical and Chemical Properties 
Physical State:  Crystalline powder
Color: White
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 195-196°C/17mm
Freezing/Melting Point: 155 - 156 °C
Autoignition Temperature: Not available
Flash Point: 195-196°C/17mm
Decomposition Temperature:Not available.
Solubility: Soluble
Specific Gravity/Density: Not available
Molecular Formula: C13H21ClN2O2
Molecular Weight: 272.77

Section 10 - Stability and Reactivity 
Chemical Stability: Not avaialbe.
Conditions to Avoid: Incompatible materials, expore to air.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Polymerization: has not been reported.

Section 11 - Toxicological Information 
Acute toxicity: LD50 Oral - rat - 200 mg/kg
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitization: May cause allergic skin reaction.
Germ cell mutagenicity: Genotoxicity in vitro - Ames test - Equivocal evidence.
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: no data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available
Other Studies: The toxicological properties have not been fully investigated.

Section 12 - Ecological Information 
Additional ecological information:
     General notes: Water hazard class 3

Section 13 - Disposal Considerations 
13.1 Waste treatment methods

Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.
Section 14 - Transport Information 
14.1 UN number
ADR/RID: 2811                          IMDG: 2811                            IATA: 2811
14.2 UN proper shipping name
ADR/RID:  TOXIC SOLID, ORGANIC, N.O.S. (Procaine hydrochloride)
IMDG:  TOXIC SOLID, ORGANIC, N.O.S. (Procaine hydrochloride)
IATA:  Toxic solid, organic, n.o.s. (Procaine hydrochloride)
14.3 Transport hazard class(es)
ADR/RID: 6.1                             IMDG: 6.1                               IATA: 6.1
14.4 Packaging group
ADR/RID: III                               IMDG: III                                 IATA: III
14.5 Environmental hazards
ADR/RID: no                              IMDG Marine pollutant: no      IATA: no
14.6 Special precautions for user: no data available

Section 15 - Regulatory Information 
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
      Hazard Class:T
      Risk Phrases:
             R 25 Toxic if swallowed.
             R 43 May cause sensitization by skin contact.
      Safety Phrases:
             S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
             S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.