Material Safety Data Sheet
BISMUTH TRIPHENYL   
 
Section 1 - Chemical Product and Company Identification
MSDS Name: BISMUTH TRIPHENYL
Catalog Numbers: 86-22067

Section 2 - Composition, Information on Ingredients 
CAS#603-33-8
Chemical Name: BISMUTH TRIPHENYL   
Percent  99%
EINECS/ELINCS: 210-033-4.
Hazard Symbols: Xn.
Risk Phrases: 20/21/22 .

OSHA Hazards
Target Organ Effect, Toxic by inhalation., Harmful by ingestion., Harmful by skin absorption.
Target Organs: Central nervous system, Kidney
GHS Classification
Acute toxicity, Oral (Category 4)
Acute toxicity, Inhalation (Category 4)
Acute toxicity, Dermal (Category 4)
GHS Label elements, including precautionary statements
Pictogram 
Signal word: Warning
Hazard statement(s)
H302 + H312: Harmful if swallowed or in contact with skin.
H332: Harmful if inhaled.
Precautionary statement(s)
P280 Wear protective gloves/ protective clothing.
HMIS Classification
Health hazard: 2
Chronic Health Hazard: *
Flammability: 0
Physical hazards: 0
NFPA Rating
Health hazard: 2
Fire: 0
Statements: none
Reactivity Hazard: 0

Section 3 - Hazards Identification 
Potential Health Effects
Inhalation: Toxic if inhaled. May cause respiratory tract irritation.
Skin: Harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Ingestion: Harmful if swallowed.

Section 4 - First Aid Measures 
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Flush eyes with water as a precaution.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures 
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
Hazardous combustion products: Hazardous decomposition products formed under fire conditions. - Carbon oxides, Bismuth oxides

Section 6 - Accidental Release Measures 
Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapors, mist or gas.
Environmental precautions: Do not let product enter drains.
Methods and materials for containment and cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections: For disposal see section 13

Section 7 - Handling and Storage 
Precautions for safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.
Conditions for safe storage: Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place

Section 8 - Exposure Controls, Personal Protection 
Contains no substances with occupational exposure limit values.

Personal protective equipment
Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of Workday.

Section 9 - Physical and Chemical Properties 
Physical State: Powder.
Color: Light yellow.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
 Boiling Point: 310°C.
Melting Point: 76 °C (169 °F)
Autoignition Temperature: Not available.
 Flash Point: 242°C/14mm. 
 Decomposition Temperature: Not available.
 Density: 1,585 g/cm3
 Water solubility: insoluble
 Molecular Formula: C18H15Bi
 Molecular Weight: 440.29

Section 10 - Stability and Reactivity 
Chemical stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: no data available
Conditions to avoid: no data available
Materials to avoid: Strong oxidizing agents, Halogens, acids
Hazardous decomposition products: Hazardous decomposition products formed under fire conditions. - Carbon oxides, Bismuth oxides

Section 11 - Toxicological Information 
RTECS#: Not available.
CAS#603-33-8
LD50/LC50: RTECS: Not available.
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable,
possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Other Studies: The toxicological properties have not been fully investigated.

Section 12 - Ecological Information 
12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
no data available

Section 13 - Disposal Considerations
Waste treatment methods
Product:Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:Dispose of as unused product.

Section 14 - Transport Information 
14.1 UN number
ADR/RID: -                     IMDG: -                                                  IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: -                   IMDG: -                                                    IATA: -
14.4 Packaging group 
ADR/RID: -                   IMDG: -                                                     IATA: -
14.5 Environmental hazards
ADR/RID: no                IMDG Marine Pollutant: no                       IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information
OSHA Hazards: Target Organ Effect, Toxic by inhalation., Harmful by ingestion., Harmful by skin absorption.
DSL Status: All components of this product are on the Canadian DSL list.
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold
(De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components: No components are subject to the Massachusetts Right to Know Act.
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European/International Regulations
      European Labeling in Accordance with EC Directives
           Hazard Symbols: Not available.
           Risk Phrases:
                    R20/21/22Harmful by inhalation, in contact with skin and if swallowed
           Safety Phrases:
                    S24/25 Avoid contact with skin and eyes.
                    S36/37 Wear suitable protective clothing and gloves.

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.