Material Safety Data Sheet
CYCLOPROPYL KETONE

Section 1 - Chemical Product and Company Identification
MSDS Name: CYCLOPROPYL KETONE
Catalog Numbers: SC-43868

Section 2 - Composition, Information on Ingredients 
CAS#1121-37-5
Chemical Name: CYCLOPROPYL KETONE
Percent  98%
EINECS/ELINCS 214-331-5

Section 3 - Hazards Identification 
3.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 3), H226
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 GHS Label elements, including precautionary statements
Pictogram 
Signal word Warning
Hazard statement(s)
H226 Flammable liquid and vapour.
Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.  
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/ container to an approved waste disposal plant.

3.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

Section 4 - First Aid Measures 
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.

Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Avoid breathing vapours, mist or gas. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.

Section 7 - Handling and Storage 
7.1 Precautions for safe handling
Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Section 8 - Exposure Controls, Personal Protection 
8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
 
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Section 9 - Physical and Chemical Properties 
a) Appearance Form: clear, liquid            Color: dark brown
b) Odour: no data available
c) Odour Threshold: no data available
d) pH: no data available
e) Melting point/freezing point: no data available
f) Initial boiling point and boiling range: 160 - 162 °C (320 - 324 °F) - lit
g) Flash point: 39 °C (102 °F) - closed cup
h) Evapouration rate: no data available
i) Flammability (solid, gas): no data available
j) Upper/lower flammability or explosive limits: no data available
k) Vapour pressure: no data available
l) Vapour density: no data available
m) Relative density: 0.977 g/cm3 at 25 °C (77 °F)
n) Water solubility: no data available
o) Partition coefficient: noctanol/water: no data available
p) Auto-ignition temperature: no data available
q) Decomposition temperature: no data available
r) Viscosity: no data available
s) Explosive properties: no data available
t) Oxidizing properties: no data available
9.2 Other safety information: no data available

Section 10 - Stability and Reactivity 
10.1 Reactivity: no data available
10.2 Chemical stability: Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions: no data available
10.4 Conditions to avoid: Heat, flames and sparks.
10.5 Incompatible materials: Strong oxidizing agents, glass
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

Section 11 - Toxicological Information 
11.1 Information on toxicological effects
Acute toxicity: no data available
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitisation: no data available
Germ cell mutagenicity: no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: no data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available
Additional Information: RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12 - Ecological Information 
12.1 Toxicity: no data available
12.2 Persistence and degradability: no data available
12.3 Bioaccumulative potential: no data available
12.4 Mobility in soil: no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects: no data available

Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging: Dispose of as unused product

Section 14 - Transport Information 
DOT (US)
UN number: 1224 Class: 3 Packing group: III
Proper shipping name: Ketones, liquid, n.o.s. (Dicyclopropyl ketone)
Marine pollutant: No
Poison Inhalation Hazard: No
 
IMDG
UN number: 1224 Class: 3 Packing group: III EMS-No: F-E, S-D
Proper shipping name: KETONES, LIQUID, N.O.S. (Dicyclopropyl ketone)
Marine pollutant: No
 
IATA
UN number: 1224 Class: 3 Packing group: III
Proper shipping name: Ketones, liquid, n.o.s. (Dicyclopropyl ketone)

SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: no data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

Section 16 - Additional Information
Full text of H-Statements referred to under sections 2 and 3.
Flam. Liq. Flammable liquids
H226 Flammable liquid and vapour.
HMIS Rating
Health hazard: 0
Chronic Health Hazard:
Flammability: 2
Physical Hazard 0
NFPA Rating
Health hazard: 0
Fire Hazard: 2
Reactivity Hazard: 0

While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.