Section 1 - Chemical Product and Company Identification
MSDS Name: 3-(TRIFLUOROMETHYLTHIO)ANILINE
Catalog Numbers: 56-00403
Section 2 - Composition, Information on Ingredients
CAS#369-68-6
Chemical Name: 3-(TRIFLUOROMETHYLTHIO)ANILINE
Percent 97%min
EINECS/ELINCS: Not available.
Hazard Symbols: T
Risk Phrases: 20/21/22
Section 3 - Hazards Identification
Toxic
Avoid prolonged exposure.
Do Not breathe vapor.
Use caution when handling.
Exposure to any chemical should be limited.
To the best of knowledge, the health hazards of this product have not been fully investigated.
This product is provided solely for the purpose of research and development,
Section 4 - First Aid Measures
Eye Contact: Immediately flush eyes with plenty of water for at least 20 minutes.Assure adequate flushing of the eyes by separating the eyelids with
fingers. Get immediate medical attention if irritation persists, or symptomsof overexposure become apparent.
Skin Contact: Immediately wash skin with plenty of water for at least 20 minutes, whileremoving contaminated clothing and shoes. Get medical attention
especially, if irritation develops, persists, or symptoms of overexposurebecome apparent.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration or giveoxygen by trained personnel. Keep warm. Get immediate medicalattention.
Ingestion: If swallowed, call a physician or poison control center immediately. Nevergive anything by mouth to an unconscious person. Do not induce vomitingunless instructed by medical personnel. Get medical attention.
Section 5 - Fire Fighting Measures
Flash Point: No data
Extinguishing Media: Use dry powder or carbon dioxide when fighting a fire involving thismaterial.
Unsuitable Media: Water extinguishers are not recommended.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,NIOSH (approved or equivalent) and full protective gear.
Section 6 - Accidental Release Measures
Personal Precautions: Use proper personal protective equipment as listed in section 8.
Spill Cleanup Measures: Absorb spill with dry inert material such as dry sand, earth, or vermiculite,then place in suitable container. Refer to section 13 for proper disposal.
Environmental Precautions: Do not allow material to enter drains or streams.
Section 7 - Handling and Storage
Handling: This product should be handled only by, or under the close supervision of,those properly qualified in the handling and use of potentially hazardous
chemicals, who should take into account the fire, health and chemicalhazard data. It should always be handled in an efficient fume hood orequivalent system. The user should consider that the toxicological andphysiological properties of many compounds are not yet well determinedand that new hazardous products may arise from reactions betweenchemicals. Care should be taken to prevent any chemical from coming intocontact with the skin or eyes and from contaminating personal clothing.
Storage: Store in a cool, dry, well ventilated area away from sources of heat andincompatible substances. Keep container tightly closed when not in use.
Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoidinhaling vapor or mist.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use appropriate engineering control such as process enclosures, localexhaust ventilation, or other engineering controls to control airbornelevels below recommended exposure limits. Where such systems are noteffective wear suitable personal protective equipment, which performs
satisfactorily and meets OSHA or other recognized standards. Consult withlocal procedures for selection, training, inspection and maintenance of the
personal protective equipment.
Skin Protection Description: Wear suitable protective clothing to prevent contact with skin.
Hand Protection Description: Wear appropriate protective gloves. Consult glove manufacturers for glovepermeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29CFR 1910.133, OSHA eye and face protection regulation, or the Europeanstandard EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an appropriate cartridge orcanister may be permissible under certain circumstances where airborneconcentrations are expected to exceed exposure limits. Protectionprovided by air purifying respirators is limited to airborne concentrations
that are typically within 10 times the exposure limit. Use a positivepressure air supplied respirator if there is any potential for an uncontrolledrelease, exposure levels are not known, or any other circumstances whereair-purifying respirators may not provide adequate protection. Arespiratory protection program that meets OSHAs 29 CFR 1910.134 andANSI Z88.2 requirements must be followed whenever workplaceconditions warrant a respirators use.
Other Protective: Facilities storing or utilizing this material should be equipped with aneyewash facility and a safety shower.
Section 9 - Physical and Chemical Properties
Physical State/Appearance: Liquid
Flash Point: No data
Boiling Point: 221-223°C (429.8-433.4°F)
Melting Point: No data
Solubility in Water: Immiscible
Density: 1.348
Molecular Formula: C7H6F3NS
Molecular Weight: 193.19
Section 10 - Stability and Reactivity
Conditions to Avoid: High temperatures, flames and sparks.
Incompatibilities with OtherMaterials:Oxidizing agents. Strong acids.
Possible DecompositionProduct:Carbon monoxide. Hydrogen cyanide, oxides of nitrogen. Hydrogenfluoride. Oxides of sulphur.
Section 11 - Toxicological Information
Eye Effect: No data reported in the cited references as of the revision date.
Skin Effects: No data reported in the cited references as of the revision date.
Ingestion Effects: No data reported in the cited references as of the revision date.
Inhalation Effects: No data reported in the cited references as of the revision date.
Section 12 - Ecological Information
12.1 Toxicity: No data available
12.2 Persistence and degradability: No data available
12.3 Bioaccumulative potential: No data available
12.4 Mobility in soil: No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects: No data available
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
Section 14 - Transport Information
DOT Shipping Name: Toxic, liquids, organic, n.o.s. (3-(Trifluoromethylthio)aniline)
DOT Hazard Class: 6.1
DOT Identification Number: UN2810
DOT Packing Group: III
Section 15 - Regulatory Information
TSCA 8(b): Inventory Status: Not listed on the TSCA inventory.
Section 112(r): Clean Air Act(yes/no): No
Risk Phrases
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
Safety Phrase
S28 After contact with skin, wash immediately with plenty of water
S36/37 Wear suitable protective clothing and gloves.
Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities
from the use of this product or information contained herein.
HOME