Material Safety Data Sheet

Ethyl piperidine-3-carboxylate  

  

 

Section 1 - Chemical Product and Company Identification

MSDS Name: Ethyl piperidine-3-carboxylate  

 

Section 2 - Composition, Information on Ingredients 

CAS# 5006-62-2

Chemical Name: Ethyl piperidine-3-carboxylate

Percent  98%

EINECS/ELINCS: 225-681-3.

 

Section 3 - Hazards Identification

3.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Skin irritation (Category 2), H315

Eye irritation (Category 2), H319

Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Xi          Irritant               R36/37/38

For the full text of the R-phrases mentioned in this Section, see Section 16.

3.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram       

Signal word          Warning

Hazard statement(s)

H315           Causes skin irritation.

H319           Causes serious eye irritation.

H335           May cause respiratory irritation.

Precautionary statement(s)

P261     Avoid breathing vapours.

P280     Wear protective gloves.

P305 + P351 + P338       IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard Statements    none

3.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

 

Section 4 - First Aid Measures

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. 

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.  

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Section 5 - Fire Fighting Measures 

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.  

5.2 Special hazards arising from the substance or mixture

Carbon oxides, Nitrogen oxides (NOx)  

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

Use water spray to cool unopened containers.

 

Section 6 - Accidental Release Measures 

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.  

6.3 Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

Section 7 - Handling and Storage 

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Storage class (TRGS 510): Combustible liquids  

7.3 Specific end uses

no data available

Section 8 - Exposure Controls, Personal Protection 

Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.

 

Personal Protective Equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

 Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.  

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).  

Section 9 - Physical and Chemical Properties 

Physical State: Liquid.
Color: Colourless.
Odor: Not available.

pH: Not available.

Vapor Pressure: Not available.

Viscosity: Not available.

Boiling Point: Not available.
Melting point: Not available.
Autoignition Temperature: Not available.

Flash Point: Not available.

Explosion Limits: Not available.

Explosion Limits: Not available.

Decomposition Temperature: Not available.

Specific Gravity/Density: Not available.

Molecular Formula: C8H15NO2.

Molecular Weight: 157.21.

 

Section 10 - Stability and Reactivity 

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.  

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

Heat, flames and sparks.  

10.5 Incompatible materials

Strong bases, Strong oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products - No data available

In the event of fire: see section 5

 

 

Section 11 - Toxicological Information

11.1 Information on toxicological effects

Acute toxicity

No data available

Skin corrosion/irritation

Irritating to eyes, respiratory system and skin.  

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: Not available

Section 12 - Ecological Information 

12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

no data available

 

Section 13 - Disposal Considerations

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.  

Contaminated packaging

Dispose of as unused product

 

Section 14 - Transport Information 

14.1 UN number

ADR/RID: -                                  IMDG: -                                          IATA: -

14.2 UN proper shipping name

ADR/RID: Not dangerous goods

IMDG: Not dangerous goods

IATA: Not dangerous goods

14.3 Transport hazard class(es)

ADR/RID: -                                 IMDG: -                                             IATA: -

14.4 Packaging group

ADR/RID: -                                 IMDG: -                                             IATA: -

14.5 Environmental hazards

ADR/RID: no                               IMDG Marine pollutant: no               IATA: no

14.6 Special precautions for user

no data available

Section 15 - Regulatory Information 

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

15.2 Chemical Safety Assessment

no data available

Section 16 - Additional Information

Full text of H-Statements referred to under sections 2 and 3.

Eye Irrit.             Eye irritation

H315                 Causes skin irritation.

H319              Causes serious eye irritation.

H335              May cause respiratory irritation.

Skin Irrit.        Skin irritation

STOT SE       Specific target organ toxicity - single exposure

Full text of R-phrases referred to under sections 2 and 3

Xi                              Irritant

R36/37/38                 Irritating to eyes, respiratory system and skin.

 

While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.