Material Safety Data Sheet
2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE

Section 1 - Chemical Product and Company Identification
MSDS Name: 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE
Catalog Numbers: 86-49492

Section 2 - Composition, Information on Ingredients 
CAS# 330680-46-1
Chemical Name: 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE
Percent  98%
EINECS/ELINCS
Hazard Symbols: Xi
Risk Phrases: 26-36

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
Harmful if swallowed. May cause irritating to eyes, respiratory system and skin

Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin. May cause sensitization by skin contact.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Limited evidence of a carcinogenic effect.

Section 4 - First Aid Measures 
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Aspiration hazard. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. If vomiting occurs, keep head below hips to prevent aspiration into lungs.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively

Section 5 - Fire Fighting Measures 
General Information: Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use foam, dry chemical, or carbon dioxide.
Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam..

Section 6 - Accidental Release Measures 
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Use water spray to reduce vapors, do not put water directly on leak, spill area or inside container.

Section 7 - Handling and Storage 
Handling: Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - Exposure Controls, Personal Protection 
Engineering Controls: Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment
Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing:  Wear appropriate protective clothing to prevent skin exposure.
Respirators: A half-face organic vapor respirator may be worn for up to ten times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
Exposure limit(s): Reports of chronic poisoning describe anemia, decreased blood cell count and bone marrow hypoplasia. Liver and kidney damage may occur. Repeated or prolonged contact has a defatting action, causing drying, redness, dermatitis. Exposure to toluene may affect the developing fetus.

Section 9 - Physical and Chemical Properties 
Physical State:  powder
Color: Slight yellow to orange
Odor: Not available
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: N/A
Freezing/Melting Point: N/A
Autoignition Temperature: N/A
Flash Point: N/A
Upper exp. Limit: N/A
Lower exp. Limit: N/A
Fire Potential: Flammable liquid and vapor.
Decomposition Temperature:Not available.
vapor pressure: N/A
Solubility:
Specific Gravity/Density: N/A
Molecular Formula: C21H17N3O6
Molecular Weight:

Section 10 - Stability and Reactivity 
Section 10 - Stability and Reactivity 
Chemical Stability: no data available
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: no data available
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information 
RTECS#:   
CAS# 330680-46-1:
LD50 :
Inhalation: no data available
Dermal: no data available

Section 12 - Ecological Information 
Toxicity: a health hazard

Section 13 - Disposal Considerations
Recommendation: Consult state, local or national regulations for proper disposal. Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - Transport Information 
Shipping Name: Toluene disproportionation catalyst ZA-90
UN Number: 1294
Packing Group: II
WGK Germany: 2

Section 15 - Regulatory Information 
European Labeling in Accordance with EC Directives
      Hazard Class: F,Xn,T
      Risk Phrases:
             R 36/37/38 Irritating to eyes, respiratory system and skin
      Safety Phrases:
             S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
             S 36 Wear suitable protective clothing
.
Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.