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1,3-Dichloro-2-Propanol

Material Safety Data Sheet
     1,3-Dichloro-2-Propanol
 
Section 1 - Chemical Product and Company Identification
MSDS Name: 1,3-Dichloro-2-Propanol
Catalog Numbers: 86-08305

Section 2 - Composition, Information on Ingredients 
CAS#96-23-1
Chemical Name:1,3-Dichloro-2-Propanol
Percent  98%
EINECS/ELINCS: 202-491-9 .
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Carcinogenicity (Category 1B)
Acute toxicity, Oral (Category 3)
Acute toxicity, Dermal (Category 4)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
May cause cancer. Toxic if swallowed. Harmful in contact with skin.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram                                      
Signal word                                        Danger
Hazard statement(s)
H301                                                 Toxic if swallowed.
H312                                                  Harmful in contact with skin.
H350                                                  May cause cancer.
Precautionary statement(s)
P201                                                    Obtain special instructions before use.
P280                                                    Wear protective gloves/ protective clothing.
P301 + P310                                        IF SWALLOWED: Immediately call a POISON CENTER or doctor/ Physician.
P308 + P313                                        IF exposed or concerned: Get medical advice/ attention.
Supplemental Hazard Statements        none

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
Harmful if absorbed through skin. May cause skin irritation.

Potential Health Effects
Eye: May cause eye irritation.
Skin: Harmful if absorbed through skin. May cause skin irritation.
Ingestion: Toxic if swallowed.
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures 
Eyes:In case of eye contact,Flush eyes with water as a precaution.
Skin: In case of skin contact,Wash off with soap and plenty of water.
Ingestion: If swallowed,Never give anything by mouth to an unconscious person. Rinse mouth with water.
Inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.

Section 6 - Accidental Release Measures 
Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapors, mist or gas.
Environmental precautions: Do not let product enter drains.
Methods and materials for containment and cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections: For disposal see section 13


Section 7 - Handling and Storage 
Precautions for safe handling: Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Store under inert gas.

Section 8 - Exposure Controls, Personal Protection 
Engineering Controls: Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment
Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: WHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9 - Physical and Chemical Properties 
Physical State: Liquid.
Color:  Colourless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
 Boiling Point:174,3 °C.
Freezing/Melting Point: 4 °C.
Autoignition Temperature: Not available.
 Flash Point: 86 °C - closed cup .
Decomposition Temperature: Not available.
 Specific Gravity/Density: 1,351 g/mL at 25 °C1,363 g/mL at 20 °C.
 Molecular Formula: C3H6Cl2O .
 Molecular Weight: 128.99  .

Section 10 - Stability and Reactivity 
Chemical Stability: Not available.
Conditions to Avoid: Heat, flames and sparks..
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Not available.
Hazardous Polymerization: has not been reported.

Section 11 - Toxicological Information 
RTECS#: UB1400000 .
CAS#96-23-1
LD50/LC50: RTECS: UB1400000 .
Carcinogenicity:IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human
carcinogen by IARC.
Other Studies: The toxicological properties have not been fully investigated.

Section 12 - Ecological Information 
12.1 Toxicity
Toxicity to fish                                                                      LC50 - Carassius auratus (goldfish) - 680 mg/l - 24 h
Toxicity to daphnia and other aquatic invertebrates            EC50 - Daphnia magna (Water flea) - 983 mg/l - 24 h
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
no data available

Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product: This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging: Dispose of as unused product.

Section 14 - Transport Information
14.1 UN number
ADR/RID: 2750                                 IMDG: 2750                                         IATA: 2750
14.2 UN proper shipping name
ADR/RID:  1,3-DICHLOROPROPANOL-2
IMDG:  1,3-DICHLOROPROPANOL-2
IATA:  1,3-Dichloropropanol-2
14.3 Transport hazard class(es)
ADR/RID: 6.1                                    IMDG: 6.1                                              IATA: 6.1
14.4 Packaging group
ADR/RID: II                                        IMDG: II                                                 IATA: II
14.5 Environmental hazards
ADR/RID: no                                       IMDG Marine pollutant: no                    IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information
European/International Regulations
      European Labeling in Accordance with EC Directives
           Hazard Symbols: T,F .
           Risk Phrases:
                   R45 May cause cancer.
                   R21 Also harmful in contact with skin.
                   R25 Also toxic if swallowed.
           Safety Phrases:
                  S53 Avoid exposure - obtain special instructions before use.
                  S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities
from the use of this product or information contained herein.