Section 1 - Chemical Product and Company Identification
MSDS Name: 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
Catalog Numbers: SC-19662
Section 2 - Composition, Information on Ingredients
CAS# 12150-46-8
Chemical Name: 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
Percent 98%
EINECS/ELINCS 430-420-3
Hazard Symbols: T
Risk Phrases: 25-36/37/38-20/21/22
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Toxic if swallowed.Air sensitive
Potential Health Effects
Eye: Cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin: Cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion: Cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic: No information found.
Section 4 - First Aid Measures
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively
Section 5 - Fire Fighting Measures
General Information: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood..
Storage: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:Wear appropriate protective eyeglasses.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - Physical and Chemical Properties
Physical State: Crystalline
Color: Yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point:: Not available
Freezing/Melting Point:: 181-183 Deg C
Autoignition Temperature: Not available
Flash Point: Not available
Decomposition Temperature:Not available.
Solubility: Insoluble
Specific Gravity/Density:
Molecular Formula: C34H28FeP2
Molecular Weight:: 553.99
Section 10 - Stability and Reactivity
Chemical Stability: Not avaialbe.
Conditions to Avoid: Incompatible materials, expore to air.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, oxides of phosphorus, carbon dioxide, phosphine..
Hazardous Polymerization: has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 12150-46-8:
Carcinogenicity:1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 98% - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other Studies: The toxicological properties have not been fully investigated.
Section 12 - Ecological Information
Not available
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
Shipping Name: ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S.*
UN Number: 3467
Packing Group: III
WGK Germany: not available
Section 15 - Regulatory Information
European Labeling in Accordance with EC Directives
Hazard Class:T
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 25 Toxic if swallowed
R 36/37/38 Irritating to eyes, respiratory system and skin
Safety Phrases:
S 22 Do not breathe dust
S 24/25 Avoid contact with skin and eyes
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S 28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S 36 Wear suitable protective clothing
Canada
CAS# 12150-46-8 is listed on Canada's NDSL List
US Federal
TSCA
CAS# 12150-46-8 is listed on the TSCA Inventory. It is for research and development use only.
Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.
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